Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

Calculation of transverse hydrodynamic coefficients using computational fluid dynamic approach   总被引：1，自引：0，他引：1  

Amit Tyagi  Debabrata Sen 《Ocean Engineering》2006,33(5-6):798-809

Computational Fluid Dynamic (CFD) based on Reynolds Averaged Navier–Stokes equation is used for determining the transverse hydrodynamic damping force and moment coefficients that are needed in the maneuverability study of marine vehicles. Computations are performed for two geometrical shapes representing typical AUVs presently in use. Results are compared with available data on similar geometries and from some of the available semi-empirical relations. It is found that the CFD predictions compares reasonable well with these results. In particular, the CFD predictions of forces and moments are found to be nonlinear with respect to the transverse velocity, and therefore both linear and nonlinear coefficients can be derived. A discussion on the sources of the component forces reveal that the total force and moment variations should in fact be nonlinear.  相似文献   

比较原理在多有理数时滞区间系数离散系统的应用     

张彩虹  高存臣 《中国海洋大学学报(自然科学版)》2006,36(Z1):219-221

应用多组有理数时滞离散系统的比较原理和频域法,将多组有理数时滞区间系数离散系统化为多组有理数时滞定常离散系统,以判定其时滞无关稳定性,并举例说明了新定理的有效性和实用性。  相似文献   

一种推广的缓坡方程   总被引：4，自引：3，他引：4  

潘军宁  洪广文等 《海洋工程》2001,19(1):24-31

从流体力学基本方程出发，假定水流的涡量和垂向流速分量小量，推导出考虑非均匀水流的推广的缓坡方程，该方程中包含了△h^2h项和（△hh)^2项。在方程中引入底摩擦项、风能输入项和非线性项，其中风能输入项的推导考虑了风浪与涌浪的区别，风流情况依据青岛海洋大学的风浪成长经验关系，涌浪情况依据Snyder等人的观测结果。经过上述推广后，得到综合考虑折射、绕射、反射、非均匀水流、底摩擦损耗、风能输入及波浪非线性的推广的缓坡方程。  相似文献   

Separation of Waves by Interpolation Method     

孙鹤泉  王永学 《中国海洋工程》2003,17(1)

1 .ＩｎｔｒｏｄｕｃｔｉｏｎＴｏｍｅａｓｕｒｅｔｈｅｒｅｆｌｅｃｔｉｏｎｏｆｉｎｃｉｄｅｎｔｗａｖｅｓｐｒｏｄｕｃｅｄｂｙａｐｈｙｓｉｃａｌｍｏｄｅｌｉｎａｗａｖｅｆｌｕｍｅｉｓａｃｏｍｍｏｎｐｒｏｂｌｅｍｗｉｔｈｐｈｙｓｉｃａｌｔｅｓｔｓｏｆｗａｖｅａｃｔｉｏｎｏｎｃｏａｓｔａｌｓｔｒｕｃｔｕｒｅｓ .Ｗａｖｅｓｇｅｎｅｒａｔｅｄｂｙｔｈｅｗａｖｅ ｍａｋｅｒｐｒｏｐａｇａｔｅｆｏｒｗａｒｄｉｎｔｈｅｗａｖｅｆｌｕｍｅａｎｄａｒｅｒｅｆｌｅｃｔｅｄｂｙｔｈｅｐｈｙｓｉｃａｌｍｏｄｅｌ,ａｎｄｔｈｅ…  相似文献   

规则波在缓坡上变形与破碎数值分析     

李玉成  肖辉 《海洋工程》2007,25(1):27-34

通过在二维数值水槽内用边界元法直接求解Laplace方程,对规则波在缓坡上的变形及破碎进行了数值计算。分析了不同底坡及采用不同底摩阻系数时规则波的破碎特征,并对规则波破碎的极限坡度进行了研究。重点分析了规则波破碎时海底坡度、底摩阻系数及波形不对称性对破碎指标的影响。  相似文献   

On the radiation and diffraction of linear water waves by an infinitely long rectangular structure submerged in oblique seas   总被引：1，自引：0，他引：1  

Y.H. Zheng  P.F. Liu  Y.M. Shen  B.J. Wu  S.W. Sheng 《Ocean Engineering》2007,34(3-4):436-450

The radiation and diffraction of linear water waves by an infinitely long rectangular structure submerged in oblique seas of finite depth is investigated. The analytical expressions for the radiated and diffracted potentials are derived as infinite series by use of the method of separation of variables. The unknown coefficients in the series are determined by the eigenfunction expansion matching method. The expressions for wave forces, hydrodynamic coefficients and reflection and transmission coefficients are given and verified by the boundary element method. Using the present analytical solution, the hydrodynamic influences of the angle of incidence, the submergence, the width and the thickness of the structure on the wave forces, hydrodynamic coefficients, and reflection and transmission coefficients are discussed in detail.  相似文献   

海洋测绘中影像图与港口航道图的镶嵌技术运用     

奉定平  邢攸姿 《海洋技术学报》2007,26(3):94-96

文中介绍陆地影像图与港口航道图镶嵌的制图工艺,影像图与港口航道图镶嵌后的成图质量评价。简单阐述了作者在绘制该图种过程中的一些体会,以及影像图取代现有港口航道图上陆地地形的可行性。  相似文献   

Parameterization of Wave Breaking Probability and Whitecap Coverage     

李晶于定勇  刘华兴 《中国海洋工程》2006,20(3):411-418

1 .Introduction Wave breaking and associated whitecapping have long beeninteresting due totheir close relationto many fields of ocean study,including air-sea interaction,remote sensing,ocean engineering,aswell as wave dynamics .The breaking probabilityBan…  相似文献   

双层局部开孔板沉箱对波浪反射的理论研究   总被引：1，自引：0，他引：1  

李玉成  刘洪杰滕斌 《海洋工程》2005,23(1):18-27,32

提出了一种用于研究由双层开孔板和一个不透水后板的开孔结构对斜向波反射率的理论分析方法。整个流域被分成三个子域，在每个子域内应用特征函数展开法以得到该域内包含未知展开系数的势函数的表达式，在速度势的展开中，考虑了非传播模态波浪的影响。通过匹配开孔板处的边界条件可以求解待定的展开系数，继而求解双层开孔板防波堤结构对斜向波的反射率。数值计算结果与试验结果进行了比较，符合较好。并进一步讨论了几个重要因素对反射系数的影响。  相似文献